Anti-leukemia Activity of 7-hydroxy-2-substituted-methyl-5 H -oxazolo[3,2- a] pyrimidin-5-one Derivatives

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SELECTIVE CYCLIZATION OF 2-PROPARGYLTHIO-6-METHYL-PYRIMIDIN- 4(1 H)-ONE TO THIAZOLO [3,2-a] PYRIMIDIN 7-ONE

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selective cyclization of 2-propargylthio-6-methyl-pyrimidin- 4(1 h)-one to thiazolo [3,2-a] pyrimidin 7-one

selective transformation of 2-propargylthio-6-methyl-pyrimidin-4(1h)on e (2) to 3,5-dimethyl-7h-thiazolo [3,2-a] pyrimidin-7-one (3) is performed under the conditionof base catalysis . for elucidation of structure, palladium catalyzed cyclization reaction of (2) was carried out and the structures of the products were assigned (5) and (6). these compounds underwent isomerization to (3) and (4) r...

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ژورنال

عنوان ژورنال: Journal of Enzyme Inhibition and Medicinal Chemistry

سال: 2002

ISSN: 1475-6366,1475-6374

DOI: 10.1080/1475636021000005668